Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
He, X.*; Kagi, Hiroyuki*; Komatsu, Kazuki*; Iizuka, Riko*; Okajima, Hajime*; Hattori, Takanori; Sano, Asami; Machida, Shinichi*; Abe, Jun*; Goto, Hirotada*; et al.
Journal of Molecular Structure, 1310, p.138271_1 - 138271_8, 2024/08
High-pressure responses of the O-D
F hydrogen bonds in deuterated magnesium hydroxyfluoride were investigated using neutron powder diffraction and Raman spectroscopy. The Rietveld analysis at ambient conditions revealed a chemical formula of Mg(OD)
F
and hydroxyl group/fluorine disorder (OD/F disorder) in the crystal structure, which gave rise to two hydrogen-bonding configurations. The Rietveld analysis showed the hydrogen-bonding geometries remains up to 9.8 GPa, indicating no pressure-induced strengthening of hydrogen bonds. The Raman spectra at ambient conditions showed three hydroxyl stretching bands at 2613, 2694, and 2718 cm
. The high frequencies of the O-D stretching modes indicated that the hydroxyls should be involved in weak or none hydrogen-bonding interactions. Up to 20.2 GPa, the mode initially centered at 2694 cm displayed a pressure-induced blue shift, revealing no strengthening of hydrogen bonds under compression. We discuss the existence of hydrogen bonds and the causes of the blue-shifting hydroxyls at ambient and at high pressures.
Sanada, Yukihisa; Oshikiri, Keisuke*; Kanno, Marina*; Abe, Tomohisa
Nuclear Instruments and Methods in Physics Research A, 1062, p.169208_1 - 169208_7, 2024/05
As part of the decommissioning work at the Fukushima Daiichi Nuclear Power Plant (FDNPP), the release of stored treated water began in 2023. In this study, we developed a practical tritium monitor to continuously monitor the concentration of tritiated water, as confirmed by batch sampling measurements at the FDNPP. The monitor is arranged with a flow cell detector comprising inexpensive plastic scintillator pellets and incorporating simultaneous measurements by three detectors, a veto detector, and lead shielding to reduce the influence of environmental 
-rays. The system reached a detection limit of 911 Bq L-1 with a measurement time of 30 min, which is lower than the discharge standard for tritiated water of 1,500 Bq L-1. The system can also qualitatively distinguish the presence of disturbances due to interfering radionuclides other than tritium or background radiation using the 
-ray spectrum.
Fujihara, Hiro*; Toda, Hiroyuki*; Ebihara, Kenichi; Kobayashi, Masakazu*; Mayama, Tsuyoshi*; Hirayama, Kyosuke*; Shimizu, Kazuyuki*; Takeuchi, Akihisa*; Uesugi, Masayuki*
International Journal of Plasticity, 174, p.103897_1 - 103897_22, 2024/03
Times Cited Count：0Hydrogen(H) embrittlement in high-strength aluminum(Al) alloys is a crucial problem. H accumulation at the interface of precipitates in Al alloy is considered to cause embrittlement. However, there is no quantitative knowledge regarding the interaction between H distribution and stress field near cracks. In this study, using a multi-modal three-dimensional image-based simulation combining the crystal plasticity finite element method and H diffusion analysis, we tried to capture the stress distribution near the crack, its influence on the H distribution, and the probability of crack initiation in the experimental condition. As a result, it was found that grain boundary cracks transition to quasi-cleavage cracks in the region where the cohesive energy of the semi-coherent interface of MgZn
precipitates decreases due to H accumulation near the tip. We believe the present simulation method successfully bridges nanoscale delamination and macroscale brittle fracture.
Yamamoto, Yusuke*; Watanabe, Takahiro; Niwa, Masakazu; Shimada, Koji
JAEA-Testing 2023-003, 67 Pages, 2024/02
JAEA-Testing-2023-003.pdf:4.63MB
A long-term geosphere stability for geological disposal is evaluated by the past geological environmental changes and modern conditions. Stable hydrogen and oxygen isotope ratios (
D, 
O) of geological samples are useful information to estimate the past environmental changes and modern conditions. Recently, the thermal conversion elemental analyzer and isotope ratio mass spectrometer (TC-EA/IRMS) were installed in the Tono Geoscience Center for D and O measurements of geological samples. In this study, we reported analytical methods of D and O using international standard reference materials. In addition, evaluation tests of uncertainty by repeated analyses of the standards were performed using the TC-EA/IRMS. Furthermore, the D and O analyses by the TC- EA/IRMS were also applied to fault rock samples.
Takeuchi, Ryuji; Kokubu, Yoko; Nishio, Kazuhisa*
JAEA-Data/Code 2023-014, 118 Pages, 2024/02
JAEA-Data-Code-2023-014.pdf:4.77MB
JAEA-Data-Code-2023-014-appendix(CD-ROM).zip:249.03MB
The Tono Geoscience Center of Japan Atomic Energy Agency (JAEA) has been conducting the groundwater pressure and hydro-chemical monitoring to confirm the restoration process of the surrounding geological environment associated with the backfilling of shafts and tunnels of Mizunami Underground Research Laboratory (MIU). This report summarizes the data of the groundwater pressure and hydro-chemical monitoring from boreholes and forth at and around the MIU conducted in FY2022. In addition, unreported hydro-chemical monitoring data from the boreholes and forth at the MIU conducted in FY2021 were also compiled.
Aoyagi, Kazuhei; Ishii, Eiichi
Environmental Earth Sciences, 83(3), p.98_1 - 98_15, 2024/02
Times Cited Count：0 Percentile：0.04(Environmental Sciences)The long-term geological disposal of high-level radioactive waste relies on predictions of future changes in a disposal facility's hydro-mechanical characteristics to assess potential leakage through fractures in the excavation damaged zone (EDZ) after backfilling the facility. This study evaluated the transmissivity of EDZ fractures using in situ hydraulic tests around the area of a full-scale, experimental, engineered barrier system in the Horonobe Underground Research Laboratory, Hokkaido, Japan. After their installation, the buffer blocks swelled, altering the stresses within the EDZ fractures. The effects of these changing stresses on the fractures' transmissivity were assessed over a period of 4 years. The transmissivity continuously decreased in this period to about 41% of its value measured prior to the swelling. Using the Barton-Bandis normal-stress-dependent fracture-closure model, the decrease in transmissivity is quantitatively attributed to closure of the EDZ fractures, which was caused by the swelling pressure increasing up to 0.88 MPa. Evidence of fracture closure came from seismic tomography surveying, which revealed a slight increase in seismic velocity in the study area with increasing swelling pressure. The results show that EDZ fractures were closed by swelling of the full-scale buffer material. They also demonstrate the applicability of the Barton-Bandis model to preliminary estimation of the long-term transmissivity of EDZ fractures in facilities for the geological disposal of radioactive waste.
Takai, Shizuka; Shimada, Taro; Takeda, Seiji; Koike, Katsuaki*
Mathematical Geosciences, 56(2), p.333 - 360, 2024/02
Times Cited Count：0 Percentile：0.01(Geosciences, Multidisciplinary)To enable proper remediation of accidental groundwater contamination, the contaminant plume evolution needs to be accurately estimated. In the estimation, uncertainties in both the contaminant source and hydrogeological structure should be considered, especially the temporal release history and hydraulic transmissivity. Although the release history can be estimated using geostatistical approaches, previous studies use the deterministic hydraulic property field. Geostatistical approaches can also effectively estimate an unknown heterogeneous transmissivity field via the joint data use, such as a combination of hydraulic head and tracer data. However, tracer tests implemented over a contaminated area necessarily disturb the in situ condition of the contamination. Conversely, measurements of the transient concentration data over an area are possible and can preserve the conditions. Accordingly, this study develops a geostatistical method for the joint clarification of contaminant plume and transmissivity distributions using both head and contaminant concentration data. The applicability and effectiveness of the proposed method are demonstrated through two numerical experiments assuming a two-dimensional heterogenous confined aquifer. The use of contaminant concentration data is key to accurate estimation of the transmissivity. The accuracy of the proposed method using both head and concentration data was verified achieving a high linear correlation coefficient of 0.97 between the true and estimated concentrations for both experiments, which was 0.67 or more than the results using only the head data. Furthermore, the uncertainty of the contaminant plume evolution was successfully evaluated by considering the uncertainties of both the initial plume and the transmissivity distributions, based on their conditional realizations.
Naoe, Takashi; Wakui, Takashi; Kinoshita, Hidetaka; Kogawa, Hiroyuki; Teshigawara, Makoto; Haga, Katsuhiro
JAEA-Technology 2023-022, 81 Pages, 2024/01
JAEA-Technology-2023-022.pdf:9.87MB
In the liquid mercury target system for the pulsed spallation neutron source of Materials and Life Science Experimental Facility (MLF) in the Japan Proton Accelerator Research Complex (J-PARC), pressure waves that is generated by the high-energy proton beam injection simultaneously with the spallation reaction, resulting severe cavitation erosion damage on the interior surface of the mercury target vessel. Because the bubble of pressure wave-induced cavitation collapsing near the interior surface of the mercury target vessel with applying the large amplitude of localized impact on the surface. Since the wall thickness of the beam entrance portion of the target vessel is designed to be 3 mm to reduce thermal stress due to the internal heating, the erosion damage has the possibility to cause the vessel fatigue failure and mercury leakage originated from erosion pits during operation. To reduce the erosion damage by cavitation, a technique of gas microbubble injection into the mercury for pressure wave mitigation, and double-walled structure of the beam window of the target vessel has been applied. A specimen was cut from the beam window of the used mercury target vessel in order to investigate the effect of the damage mitigation technologies on the vessel, and to reflect the consideration of operation condition for the next target. We have observed cavitation damage on interior surface of the used mercury target vessel by cutting out the disk shape specimens. Damage morphology and depth of damaged surface were evaluated and correlation between the damage depth and operational condition was examined. The result showed that the erosion damage by cavitation is extremely reduced by injecting gas microbubbles and the damage not formed inside narrow channel of the double-walled structure for relatively high-power operated target vessels.
Ikeda, Kazutaka*; Sashida, Sho*; Otomo, Toshiya*; Oshita, Hidetoshi*; Honda, Takashi*; Hawai, Takafumi*; Saito, Hiraku*; Ito, Shinichi*; Yokoo, Tetsuya*; Sakaki, Koji*; et al.
International Journal of Hydrogen Energy, 51(Part A), p.79 - 87, 2024/01
Times Cited Count：0 Percentile：0.01(Chemistry, Physical)Kamewari, Ryusei*; Fujishima, Yusuke*; Kawabata, Kuniaki; Suzuki, Kenta; Sakagami, Norimitsu*; Takemura, Fumiaki*; Takahashi, Satoru*
Proceedings of the IUTAM Symposium on Optimal Guidance and Control for Autonomous Systems 2023 (IUTAM Bookseries No.40), p.85 - 101, 2024/01
Tang, J.*; Wang, Y.*; Fujihara, Hiro*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Ebihara, Kenichi; Takeuchi, Akihisa*; Uesugi, Masayuki*; Toda, Hiroyuki*
Scripta Materialia, 239, p.115804_1 - 115804_5, 2024/01
Times Cited Count：0 Percentile：0(Nanoscience & Nanotechnology)Stress corrosion cracking (SCC) behaviors induced by the combination of external and internal hydrogen (H) in an Al-Zn-Mg-Cu alloy were systematically investigated via in situ 3D characterization techniques. SCC of the Al-Zn-Mg-Cu alloy could initiate and propagate in the potential crack region where the H concentration exceeded a critical value, in which the nanoscopic H-induced decohesion of 
-MgZn precipitates resulted in macroscopic cracking. External H that penetrated the alloy from the environment played a crucial role during the SCC of the Al-Zn-Mg-Cu alloy by generating gradient-distributed H-affected zones near the crack tips, which made Al alloys in water environment more sensitive to SCC. Additionally, the pre-existing internal H was driven toward the crack tips during plastic deformation. It was involved in the SCC and made contributions to both the cracks initiation and propagation.
Saito, Takumi*; Nishi, Shusaku*; Amano, Yuki; Beppu, Hikari*; Miyakawa, Kazuya
ACS ES&T Water (Internet), 3(12), p.4103 - 4112, 2023/12
Ga K-edge XANES study of Ga-exchanged zeolites at high temperatures under different atmospheres including vacuum, CO, and pressurized H
Huang, M.*; Kinjo, Tetsuya*; Yasumura, Shunsaku*; Toyao, Takashi*; Matsumura, Daiju; Saito, Hiroyuki*; Shimizu, Kenichi*; Namiki, Norikazu*; Maeno, Zen*
Catalysis Science & Technology, 13(23), p.6832 - 6838, 2023/12
Times Cited Count：0 Percentile：0(Chemistry, Physical)
neutron diffractionKobayashi, Hiroki*; Komatsu, Kazuki*; Ito, Hayate*; Machida, Shinichi*; Hattori, Takanori; Kagi, Hiroyuki*
Journal of Physical Chemistry Letters (Internet), 14(47), p.10664 - 10669, 2023/11
Times Cited Count：0 Percentile：0.01(Chemistry, Physical)Ice IV is a metastable high-pressure phase of ice in which the water molecules exhibit orientational disorder. Although orientational ordering is commonly observed for other ice phases, it has not been reported for ice IV. We conducted powder neutron diffraction experiments for DCl-doped DO ice IV to investigate hydrogen ordering in ice IV. We found abrupt changes in the temperature derivative of unit cell volume, dV/dT, at about 120 K, and revealed their slightly ordered structure at low temperatures based on the Rietveld method. The occupancy of the D1 site deviates from 0.5; it increased when samples were cooled at higher pressures and reached 0.282(5) at 2.38 GPa, 58 K. Our results evidence the presence of a low-symmetry hydrogen-ordered state corresponding to ice IV. It seems, however, difficult to experimentally access the completely ordered phase corresponding to ice IV by slow cooling at high pressure.
Higa, Ryota*; Fujihara, Hiro*; Toda, Hiroyuki*; Kobayashi, Masakazu*; Ebihara, Kenichi; Takeuchi, Akihisa*
Keikinzoku, 73(11), p.530 - 536, 2023/11
In Al-Zn-Mg alloys, suppression of hydrogen embrittlement is necessary to improve their strength. In this study, the distribution of stress, strain, and hydrogen concentration in the actual fracture region was investigated using the crystal plasticity finite element method and hydrogen diffusion analysis based on a model derived from three-dimensional polycrystalline microstructural data obtained by X-ray CT. In addition, the distributions of stress, strain, and hydrogen concentration were compared with the actual crack initiation behavior by combining in-situ observation of tensile tests using X-ray CT and simulation. The results show that stress loading perpendicular to the grain boundary due to crystal plasticity dominates grain boundary crack initiation. It was also found that internal hydrogen accumulation due to crystal plasticity has little effect on crack initiation.
Sr (
Sr) from port of Fukushima Daiichi Nuclear Power Plant; Analysis of the temporal variation from the accident to March 2022 and evaluation of its impact on Fukushima coast and offshore areasMachida, Masahiko; Iwata, Ayako; Yamada, Susumu; Otosaka, Shigeyoshi*; Kobayashi, Takuya; Funasaka, Hideyuki*; Morita, Takami*
Nihon Genshiryoku Gakkai Wabun Rombunshi (Internet), 22(4), p.119 - 139, 2023/11
We estimate monthly discharged inventory of Sr from port of Fukushima Daiichi Nuclear Power Plant (1F) from Jun. 2013 to Mar. 2022 by using the Voronoi tessellation method inside the port, following the monitoring of Sr sea water radioactivity concentration inside the port. The results suggest that the closure of sea side impermeable wall is the most effective for the reduction of discharged one. In addition, the results roughly reveal the monthly discharged inventory required to observe visible enhancement of the sea radioactivity concentration from the background level in each area. Such outcome is significant for considering environmental impacts on the planned future releasing of the treated water accumulated in 1F site.
Shinto, Katsuhiro; Okoshi, Kiyonori; Shibata, Takanori*; Nammo, Kesao*; Kawai, Isao*; Ikegami, Kiyoshi*; Ueno, Akira
Proceedings of 20th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.928 - 931, 2023/11
J-PARC initiated the operation of the high-intensity rf-driven negative hydrogen (H
) ion source in 2014 autumn. The ion source produces the H beam with the beam current of 60 mA and the beam energy of 50 keV in order to inject the H beam into the 3 GeV RCS with the beam current of 50 mA and the beam energy of 400 MeV from the J-PARC linac. We have achieved the longest continuous operation time of 4001 hours in the previous (2021/2022) campaign. The 2022/2023 campaign was the first time that the continuous operation of the H ion source without any exchanges of the ion source until the end of the campaign was examined. We present the operation status of the J-PARC H ion source in this campaign as well as the status of the J-PARC-made internal antenna test.
Shinto, Katsuhiro; Shibata, Takanori*; Wada, Motoi*
Proceedings of 20th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.392 - 395, 2023/11
Negative hydrogen (H) ion sources which are used at high-intensity proton accelerator facilities such as J-PARC or neutral beam injection system for plasma heating in the fusion devices such as ITER produce plasmas by using RF sources driving with the frequency of 1-2 MHz. We have shown that the H beams extracted from the RF-driven H ion source with the frequency of several MHz have some fluctuations with the frequency of the fundamental and second harmonics. The reason is that the high plasma density is produced in the ion source with the low driving frequency. Therefore, we propose the driving RF frequency same as the RF sources with that of 324 MHz in the J-PARC linac, which is much higher than the ion plasma frequency, is used for producing the plasma to suppress the H beam fluctuations. As a first step, we performed a design of a matching circuit for the higher frequency driven H ion source. We present the background for decision of a new RF amplifier with much higher frequency and the design results.
Yamashita, Keishiro*; Nakayama, Kazuya*; Komatsu, Kazuki*; Ohara, Takashi; Munakata, Koji*; Hattori, Takanori; Sano, Asami; Kagi, Hiroyuki*
Acta Crystallographica Section B; Structural Science, Crystal Engineering and Materials (Internet), 79(5), p.414 - 426, 2023/10
Times Cited Count：0 Percentile：0.02(Chemistry, Multidisciplinary)The structure of a recently-found hyperhydrated form of sodium chloride, NaCl
13H(D)O, has been determined by single-crystal neutron diffraction at 1.7 GPa and 298 K. It has large hydrogen-bond networks and some water molecules have distorted bonding features such as bifurcated hydrogen bonds and five-coordinated water molecules. The hydrogen-bond network has similarities to ice VI in terms of network topology and disordered hydrogen bonds. Assuming the equivalence of network components connected by pseudo symmetries, the overall network structure of this hydrate can be expressed by breaking it down into smaller structural units which correspond to the ice VI network structure. This hydrogen-bond network contains orientational disorder of water molecules in contrast to the known salt hydrates. Here, we present an example for further insights into a hydrogen-bond network containing ionic species.
Horiguchi, Naoki; Yoshida, Hiroyuki; Kaneko, Akiko*; Abe, Yutaka*
Nihon Kikai Gakkai Kanto Shibu Dai-29-Ki Sokai, Koenkai Koen Rombunshu (Internet), 5 Pages, 2023/10
To elucidate the behavior of molten fuels as a liquid jet in a shallow pool, which is assumed in a core meltdown accident of an LWR, and develop the evaluation method, we investigated the behavior of the vortical liquid film of the simulated wall-impinging liquid jet using 3-dimensional interface shape data obtained by the experiment in a liquid-liquid system.
